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Age hardenable Ni-Cr-Mo-based superalloy


Age hardenable Ni-Cr-Mo-based superalloy

Age hardenable Ni-Cr-Mo-based superalloy


Ni-based superalloys are preferred choice for high temperature applications requiring good mechanical strength as well as corrosion resistance. Ni-based alloys are broadly categorized into 3 categories: (i) Alloys containing a mainly a high amount of Cr (typically in the range 19 - 33%) and may contain small amounts of Mo (up to about 10%) for strongly oxidizing corrosive media like HNO3 acid solutions, which are commercially available as both solid-solution hardened and age age-hardened alloys; (ii) Alloys containing a high amount of Mo (typically in the range 16 - 25%) with some Cr for strongly reducing media like HCl / HF and H2SO4 acids, which are also commercially available in both solid-solution hardened and age age-hardened alloys; (iii) Alloys containing sufficiently high amounts of both Cr (in the range 16 - 22%) and Mo (in the range 13 - 16%) for multipurpose applications in both types of corrosive media, which only exist in solid-solution hardened condition. Therefore, it has long been desired to commercially exploit age-hardening to impart higher strengths to Ni-Cr-Mo alloys containing about 16 - 22% Cr and about 13 - 16% Mo. Indigenously developed age-hardenable Ni-Cr-Mo-based superalloy overcome strength limitation of solid solution hardened alloy by exhibiting much higher mechanical strength both at room temperature as well as at elevated temperatures upto about 750°C. The alloy can be easily tuned to meet the desired mechanical properties in different applications by adjusting the solutes concentration within a specific range during melting. The new alloy overcome shortcoming of Alloy 625 which get embrittle due to the formation of deleterious delta phase during service life. Its indigenously developed nature promotes self-reliance and reduces dependence on costly imports. Moreover, this technology offer showcases India's prowess in research and innovation, offering a tool that can contribute significantly in alloy and metal industries.


The newly developed alloy has been granted Indian patent vide patent no. 521226 on March 7th, 2024.


Age hardenable Ni-Cr-Mo-based superalloy

1 Age hardenable Ni-Cr-Mo-based superalloy


Indigenously developed age-hardenable Ni-Cr-Mo-based superalloy (IAHNBS) overcome strength limitation of solid solution hardened alloy by exhibiting much higher mechanical strength both at room temperature as well as at elevated temperatures upto about 750°C. The alloy can be easily tuned to meet the desired mechanical properties in different applications by adjusting the solutes concentration within a specific range during melting. Its indigenously developed nature promotes self-reliance and reduces dependence on costly imports. Moreover, this technology offer showcases India's prowess in research and innovation, offering a tool that can contribute significantly in alloy and metal industries.

SALIENT FEATURES OF IAHNBS
  1. Age-hardened alloy overcome strength limitation of commercially available Ni-Cr-Mo based alloys.
  2. Age-hardened alloy derive its strength due to coherent nano-sized precipitates of γ" phase with a Ni3(Cr,Mo,Ti,W) stoichiometry.
  3. Age-hardened alloy retain strength at elevated temperatures up to 750 °C due to high thermal stability of these precipitates up to about 800°C.
  4. Age-hardened alloy exhibits much higher room temperature yield strength (YS) and ultimate tensile strength (UTS) in the range of 427-733 MPa and 900-1210 MPa, respectively, with minimum ductility of about 40%.
  5. The alloy exhibits YS within 340-500 MPa and UTS within 640-830 MPa at 750°C, comparatively higher than commercial Ni-Cr-Mo-based alloys belonging to same family.
  6. The gamma-double prime phase forms with Ni3(Cr,Mo,Ti,W) stoichiometry without niobium, unlike the Ni3Nb gamma-double prime phase that forms in Alloy 718.
APPLICATIONS
  1. Petro-Chemical industries: reaction vessels, evaporators, stack liners, ducts, scrubbers, stack-gas re-heaters, pump and paper production, Flue gas desulfurization systems, waste treatment, tubes.
  2. Power Industries: combustion chambers, power point boiler, heat exchangers, Super-critical steam generator, automobile components.


Age hardenable Ni-Cr-Mo-based superalloy

1 Age hardenable Ni-Cr-Mo-based superalloy

Ni-based superalloys are preferred choice for high temperature applications requiring good mechanical strength as well as corrosion resistance. Ni-based alloys are broadly categorized into 3 categories: (i) Alloys containing a mainly a high amount of Cr (typically in the range 19 - 33%) and may contain small amounts of Mo (up to about 10 %) for strongly oxidizing corrosive media like HNO3 acid solutions, which are commercially available as both solid-solution hardened and age age-hardened alloys; (ii) Alloys containing a high amount of Mo (typically in the range 16 - 25%) with some Cr for strongly reducing media like HCl / HF and H2SO4 acids, which are also commercially available in both solid-solution hardened and age age-hardened alloys; (iii) Alloys containing sufficiently high amounts of both Cr (in the range 16 - 22%) and Mo (in the range 13 - 16%) for multipurpose applications in both types of corrosive media, which only exist in solid-solution hardened condition. Therefore, it has long been desired to commercially exploit age-hardening to impart higher strengths to Ni-Cr-Mo alloys containing about 16 - 22 %Cr and about 13 - 16 %Mo. Indigenously developed age-hardenable Ni-Cr-Mo-based superalloy overcome strength limitation of solid solution hardened alloy by exhibiting much higher mechanical strength both at room temperature as well as at elevated temperatures upto about 750°. The alloy can be easily tuned to meet the desired mechanical properties in different applications by adjusting the solutes concentration within a specific range during melting. Its indigenously developed nature promotes self-reliance and reduces dependence on costly imports. Moreover, this technology offer showcases India's prowess in research and innovation, offering a tool that can contribute significantly in alloy and metal .

APPLICATIONS

Potential application areas of new precipitate strengthened alloy are:

  1. Petro-Chemical industries: reaction vessels, evaporators, stack liners, ducts, scrubbers, stack-gas re-heaters, pump and paper production, Flue gas desulfurization systems, waste treatment, tubes.
  2. Power Industries: combustion chambers, power point boiler, heat exchangers, Super-critical steam generator, automobile components.
ADVANTAGES
  1. Much higher room temperature yield strength (YS) and ultimate tensile strength (UTS) in the range of 427-733 MPa and 900-1210 MPa, respectively with minimum ductility of about 40% due to the precipitation of particles with Ni3(Cr,Mo,Ti,W) stoichiometry.
  2. Potential substitute of solid-solution strengthened commercial alloys like C-22, C-276, etc.
  3. The alloy preserve age-hardenable strength within 340-500 MPa and UTS within 640-830 MPa at 750°C which is comparatively higher than commercially existing other Ni-Cr-Mo-based alloys belonging to same family.
  4. Stabilization of gamma-double prime phase with Ni3(Cr,Mo,Ti,W) stoichiometry, without niobium, unlike the main hardening Ni3Nb gamma-double prime phase in Alloy 718.
  5. High thermal stability of the Ni3(Cr,Mo,Ti,W) phase up to about 800 °C in the new alloy, unlike Ni3Nb gamma-double prime phase which transforms to deleterious delta phase at temperatures above 650 °C and embrittles the alloy.
Working Principle

The age-hardenable property in Ni-Cr-Mo based alloys have has been induced by suitable combination of Cr, Mo, W and Ti solutes to stabilizes coherent nano-sized precipitates of γ" phase with a Ni3(Cr,Mo,Ti,W) stoichiometry. The age-hardening strength at elevated temperatures up to 750 °C was achieved by high thermal stability of these precipitates up to about 800°C.

Specifications
  1. Alloy Composition: The concentration of solutes in the alloy restricted within the range: Cr=16-21%; Mo=10.5-15.8wt %; W=3.7-8.6%; Ti=1.5-2.7% and rest Ni.
  2. Trace impurities: Superalloy tolerate other elements / impurities, due to process-related additions to maximum values of 2.0% Iron (Fe), 0.50% Silicon (Si), 1.0% Manganese (Mn), 0.03% Carbon (C), 0.04% Nitrogen (N), and 0.015% Sulphur (S) and Phosphorous (P) each.
  3. Thermo-mechanical processing: At lab scale melted ingot / button must be homogenized at 1250°C for 30 h followed by either cold rolling operation followed by recrystallization heat treatment at 1200°C for 30 min or high temperature hot rolling operation at temperatures > 1150°C. Industrial scale ingot can be directly forged at temperatures 1200-1250°C.
  4. Age-hardening treatment: Solution treatment at 1100°C / 1 h followed by age-hardening treatment at 680°C for 100 h.
  5. Age-hardnened alloy must exhibit minimum hardness of 250 VHN within 100 h of ageing at 680°C.
Infrastructure Required
  1. Alloy preparation: Melting furnace, Rolling / forging equipment, Heat treatment furnaces.
  2. Characterization facility: Polishing equipment, Optical microscope, X-ray fluorescence (XRF) equipment, hardness tester, tensile testing machine.
Material Availability
  1. All raw materials are easily available in local market.
Manpower
  1. One diploma holder & 2 trained technicians to start the production.



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General License Fee : ₹ 703,800.00 (Seven Lakh Three Thousand Eight Hundred)

General Royalty : 2%